Spin engineering describes the control and manipulation of quantum spin systems to develop devices and materials. This includes the use of the spin degrees of freedom as a probe for spin based phenomena. Because of the basic importance of quantum spin for physical and chemical processes, spin engineering is relevant for a wide range of scientific and technological applications. Current examples range from Bose–Einstein condensation to spin-based data storage and reading in state-of-the-art hard disk drives, as well as from powerful analytical tools like nuclear magnetic resonance spectroscopy and electron paramagnetic resonance spectroscopy to the development of magnetic molecules as qubits and magnetic nanoparticles. In addition, spin engineering exploits the functionality of spin to design materials with novel properties as well as to provide a better understanding and advanced applications of conventional material systems. Many chemical reactions are devised to create bulk materials or single molecules with well defined spin properties, such as a single-molecule magnet. The aim of this article is to provide an outline of fields of research and development where the focus is on the properties and applications of quantum spin.

Introduction

As spin is one of the fundamental quantum properties of elementary particles it is relevant for a large range of physical and chemical phenomena. For instance, the spin of the electron plays a key role in the electron configuration of atoms which is the basis of the periodic table of elements. The origin of ferromagnetism is also closely related to the magnetic moment associated with the spin and the spin-dependent Pauli exclusion principle. Thus, the engineering of ferromagnetic materials like mu-metals or Alnico at the beginning of the last century can be considered as early examples of spin engineering, although the concept of spin was not yet known at that time. Spin engineering in its generic sense became possible only after the first experimental characterization of spin in the Stern–Gerlach experiment in 1922 followed by the development of relativistic quantum mechanics by Paul Dirac. This theory was the first to accommodate the spin of the electron and its magnetic moment.

Whereas the physics of spin engineering dates back to the groundbreaking findings of quantum chemistry and physics within the first decades of the 20th century, the chemical aspects of spin engineering have received attention especially within the last twenty years. Today, researchers focus on specialized topics, such as the design and synthesis of molecular magnets or other model systems in order to understand and harness the fundamental principles behind phenomena such as the relation between magnetism and chemical reactivity as well as microstructure related mechanical properties of metals and the biochemical impact of spin (e. g. photoreceptor proteins) and spin transport.

Research fields of spin engineering

Spintronics

Spintronics is the exploitation of both the intrinsic spin of the electron and its fundamental electronic charge in solid-state devices and is thus a part of spin engineering. Spintronics is probably one of the most advanced fields of spin engineering with many important inventions which can be found in end-user devices like the reading heads for magnetic hard disk drives. This section is divided in basic spintronic phenomena and their applications.

Basic spintronic phenomena

Applications of spintronics

this section is devoted to current and possible future applications of spintronics which make use of one or the combination of several basic spintronic phenomena:

Spin materials

Materials which properties are determined or strongly influenced by quantum spin:

  • Magnetic alloys, i.e. Heusler compounds
  • Graphene systems
  • Organic spin materials[8]
  • Molecular nanomagnets
  • Magnetic molecules
  • Organic radicals
  • Metamaterials with artificial magnetism

Spin based detection

methods to characterize materials and physical or chemical processes via spin based phenomena:

References

  1. ↑ Y Tserkovnyak; et al. (2002). "Enhanced Gilbert Damping in Thin Ferromagnetic Films". Physical Review Letters. 88 (11): 117601. arXiv:cond-mat/0110247. Bibcode:2002PhRvL..88k7601T. doi:10.1103/PhysRevLett.88.117601. PMID 11909427. S2CID 23781506.
  2. ↑ C Sandweg; et al. (2011). "Spin Pumping by Parametrically Excited Exchange Magnons". Physical Review Letters. 106 (21): 216601. arXiv:1103.2229. Bibcode:2011PhRvL.106u6601S. doi:10.1103/PhysRevLett.106.216601. PMID 21699324. S2CID 14519388.
  3. ↑ S Takahashi and S Maekawa (2008). "Spin current, spin accumulation and spin Hall effect*". Science and Technology of Advanced Materials. 9 (1): 014105. Bibcode:2008STAdM...9a4105T. doi:10.1088/1468-6996/9/1/014105. PMC 5099800. PMID 27877931.
  4. ↑ J-C Le Breton; et al. (2011). "Thermal spin current from a ferromagnet to silicon by Seebeck spin tunnelling". Nature. 475 (7354): 82–85. Bibcode:2011Natur.475...82L. doi:10.1038/nature10224. PMID 21716285. S2CID 4422579.
  5. ↑ K. Uchida; et al. (2011). "Long-range spin Seebeck effect and acoustic spin pumping". Nature Materials. 10 (10): 737–741. arXiv:1103.6120. Bibcode:2011NatMa..10..737U. doi:10.1038/nmat3099. PMID 21857673. S2CID 118009611.
  6. ↑ G E Bauer and Y Tserkovnyak (2011). "Spin-magnon transmutation". Physics. 4: 40. Bibcode:2011PhyOJ...4...40B. doi:10.1103/Physics.4.40.
  7. ↑ Y Kajiwara; et al. (2010). "Transmission of electrical signals by spin-wave interconversion in a magnetic insulator". Nature. 464 (7286): 262–266. Bibcode:2010Natur.464..262K. doi:10.1038/nature08876. PMID 20220845. S2CID 4426579.
  8. ↑ S Sanvito; et al. (2011). "Organic spintronics: Filtering spins with molecules". Nature Materials. 10 (7): 484–485. Bibcode:2011NatMa..10..484S. doi:10.1038/nmat3061. PMID 21697848.
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