Names | |
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Preferred IUPAC name
[2(2′)E]-3H,3′H-[2,2′-Bi-1-benzothiophenylidene]-3,3′-dione | |
Other names
DyStar, C.I. Vat Red 41, C.I. 73 300 | |
Identifiers | |
3D model (JSmol) |
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ChemSpider | |
ECHA InfoCard | 100.007.580 |
PubChem CID |
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UNII | |
CompTox Dashboard (EPA) |
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Properties | |
C16H8O2S2 | |
Molar mass | 296.36 g·mol−1 |
Appearance | Red solid |
Melting point | 280 °C (536 °F; 553 K) |
Insoluble | |
Solubility in ethanol, xylene | Soluble |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references |
Thioindigo is an organosulfur compound that is used to dye polyester fabric. A synthetic dye, thioindigo is related to the plant-derived dye indigo, replacing two NH groups with two sulfur atoms to create a shade of pink.
Thioindigo is generated by the alkylation of the sulfur in thiosalicylic acid with chloroacetic acid. The resulting thioether cyclizes to 2-hydroxythianaphthene, which is easily converted to thioindigo.[1] The related compound 4,7,4',7'-tetrachlorothioindigo, also a commercially important dye, can be prepared by chlorination of thioindigo.
References
- ↑ Elmar Steingruber "Indigo and Indigo Colorants" in Ullmann's Encyclopedia of Industrial Chemistry, 2004, Wiley-VCH, Weinheim. doi:10.1002/14356007.a14_149.pub2
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