Tritium oxide
All types of isotopically substituted water molecules have this structure.
Names
IUPAC name
[3H]2-water
Systematic IUPAC name
(3H2)Water
Other names
  • Super-heavy water
  • Tritium oxide
  • Ditritium oxide
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
MeSH tritium+oxide
  • InChI=1S/H2O/h1H2/i/hT2 ☒N
    Key: XLYOFNOQVPJJNP-PWCQTSIFSA-N ☒N
  • [3H]O[3H]
Properties
T2O or 3H2O
Molar mass 22.0315 g·mol−1
Appearance Colorless liquid[1]
Density 1.21 g/mL
Melting point 4.48 °C (40.06 °F; 277.63 K)[2]

[3][4]

Boiling point 101.51 °C (214.72 °F; 374.66 K)
Hazards
Occupational safety and health (OHS/OSH):
Main hazards
 corrosive and radioactive
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
☒N verify (what is checkY☒N ?)
Infobox references

Tritiated water is a radioactive form of water in which the usual protium atoms are replaced with tritium. In its pure form it may be called tritium oxide (T2O or 3H2O) or super-heavy water. Pure T2O is a colorless liquid,[1] and it is corrosive due to self-radiolysis. Diluted, tritiated water is mainly H2O plus some HTO (3HOH). It is also used as a tracer for water transport studies in life-science research. Furthermore, since it naturally occurs in minute quantities, it can be used to determine the age of various water-based liquids, such as vintage wines.

The name super-heavy water helps distinguish the tritiated material from heavy water, which contains deuterium instead.

Applications

Tritiated water can be used to measure the total volume of water in one's body. Tritiated water distributes itself into all body compartments relatively quickly. The concentration of tritiated water in urine is assumed to be similar to the concentration of tritiated water in the body. Knowing the original amount of tritiated water that was ingested and the concentration, one can calculate the volume of water in the body.

  • Amount of tritiated water (mg) = Concentration of tritiated water (mg/ml) × Volume of body water (ml)
  • Volume of body water (ml) = [Amount of tritiated water (mg) − Amount excreted (mg)] / Concentration of tritiated water (mg/ml)

Health risks

The tritium contained in tritiated water (HTO) is radioactive and a low energy beta emitter. It is not dangerous externally as its beta particles are unable to penetrate the skin. It can be a radiation hazard if inhaled, ingested via food or water, or absorbed through the skin.

While HTO is produced naturally by cosmic ray interactions in the stratosphere, it is also produced by human activities and can increase local concentrations and be considered an air and water pollutant. Anthropogenic sources of tritiated water include nuclear weapons testing, nuclear power plants, nuclear fuel reprocessing plants and consumer products such as self-illuminating watches and signs.

HTO has a short biological half-life in the human body of 7 to 14 days, which both reduces the total effects of single-incident ingestion and precludes long-term bioaccumulation of HTO from the environment. The biological half life of tritiated water in the human body, which is a measure of body water turn-over, varies with the season. Studies on the biological half life of occupational radiation workers for free water tritium in a coastal region of Karnataka, India, show that the biological half life in the winter season is twice that of the summer season.

If tritium exposure is suspected or known, drinking uncontaminated water will help replace the tritium from the body. Increasing sweating, urination or breathing can help the body expel water and thereby the tritium contained in it. However, care should be taken that neither dehydration nor a depletion of the body's electrolytes results as the health consequences of those things (particularly in the short term) can be more severe than those of tritium exposure.

References

  1. 1 2 "Tritium oxide".
  2. ↑ W. M. Jones (1952). "The Triple Point Temperature of Tritium Oxide". Journal of the American Chemical Society. 74 (23): 6065–6066. doi:10.1021/ja01143a070.
  3. ↑ "hydrogen (H) - chemical element". 6 June 2023.
  4. ↑ Paesani, Francesco; Yoo, Soohaeng; Bakker, Huib J.; Xantheas, Sotiris S. (5 August 2010). "Nuclear Quantum Effects in the Reorientation of Water". J. Phys. Chem. Lett. 1 (15): 2316–2321. doi:10.1021/jz100734w.
Wikimedia Commons has media related to Tritiated water.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.