Praseodymium, 59Pr
Praseodymium
Pronunciation/ˌpreɪziːəˈdɪmiəm/[1] ​(PRAY-zee-ə-DIM-ee-əm)
Appearancegrayish white
Standard atomic weight Ar°(Pr)
  • 140.90766±0.00001
  • 140.91±0.01 (abridged)[2]
Praseodymium in the periodic table
Hydrogen Helium
Lithium Beryllium Boron Carbon Nitrogen Oxygen Fluorine Neon
Sodium Magnesium Aluminium Silicon Phosphorus Sulfur Chlorine Argon
Potassium Calcium Scandium Titanium Vanadium Chromium Manganese Iron Cobalt Nickel Copper Zinc Gallium Germanium Arsenic Selenium Bromine Krypton
Rubidium Strontium Yttrium Zirconium Niobium Molybdenum Technetium Ruthenium Rhodium Palladium Silver Cadmium Indium Tin Antimony Tellurium Iodine Xenon
Caesium Barium Lanthanum Cerium Praseodymium Neodymium Promethium Samarium Europium Gadolinium Terbium Dysprosium Holmium Erbium Thulium Ytterbium Lutetium Hafnium Tantalum Tungsten Rhenium Osmium Iridium Platinum Gold Mercury (element) Thallium Lead Bismuth Polonium Astatine Radon
Francium Radium Actinium Thorium Protactinium Uranium Neptunium Plutonium Americium Curium Berkelium Californium Einsteinium Fermium Mendelevium Nobelium Lawrencium Rutherfordium Dubnium Seaborgium Bohrium Hassium Meitnerium Darmstadtium Roentgenium Copernicium Nihonium Flerovium Moscovium Livermorium Tennessine Oganesson
 –
↑
Pr
↓
Pa
cerium ← praseodymium → neodymium
Atomic number (Z)59
Groupf-block groups (no number)
Periodperiod 6
Block  f-block
Electron configuration[Xe] 4f3 6s2
Electrons per shell2, 8, 18, 21, 8, 2
Physical properties
Phase at STPsolid
Melting point1208 K ​(935 °C, ​1715 °F)
Boiling point3403 K ​(3130 °C, ​5666 °F)
Density (near r.t.)6.77 g/cm3
when liquid (at m.p.)6.50 g/cm3
Heat of fusion6.89 kJ/mol
Heat of vaporization331 kJ/mol
Molar heat capacity27.20 J/(mol·K)
Vapor pressure
P (Pa) 1 10 100 1 k 10 k 100 k
at T (K) 1771 1973 (2227) (2571) (3054) (3779)
Atomic properties
Oxidation states0,[3] +1,[4] +2, +3, +4, +5 (a mildly basic oxide)
ElectronegativityPauling scale: 1.13
Ionization energies
  • 1st: 527 kJ/mol
  • 2nd: 1020 kJ/mol
  • 3rd: 2086 kJ/mol
Atomic radiusempirical: 182 pm
Covalent radius203±7 pm
Color lines in a spectral range
Spectral lines of praseodymium
Other properties
Natural occurrenceprimordial
Crystal structure ​double hexagonal close-packed (dhcp)
Double hexagonal close packed crystal structure for praseodymium
Speed of sound thin rod2280 m/s (at 20 °C)
Thermal expansionα, poly: 6.7 µm/(m⋅K) (at r.t.)
Thermal conductivity12.5 W/(m⋅K)
Electrical resistivityα, poly: 0.700 µΩ⋅m (at r.t.)
Magnetic orderingparamagnetic[5]
Molar magnetic susceptibility+5010.0×10−6 cm3/mol (293 K)[6]
Young's modulusα form: 37.3 GPa
Shear modulusα form: 14.8 GPa
Bulk modulusα form: 28.8 GPa
Poisson ratioα form: 0.281
Vickers hardness250–745 MPa
Brinell hardness250–640 MPa
CAS Number7440-10-0
History
DiscoveryCarl Auer von Welsbach (1885)
Isotopes of praseodymium
Main isotopes[7] Decay
abun­dance half-life (t1/2) mode pro­duct
141Pr 100% stable
142Pr synth 19.12 h β− 142Nd
ε 142Ce
143Pr synth 13.57 d β− 143Nd

Praseodymium is a chemical element; it has symbol Pr and the atomic number 59. It is the third member of the lanthanide series and is considered one of the rare-earth metals. It is a soft, silvery, malleable and ductile metal, valued for its magnetic, electrical, chemical, and optical properties. It is too reactive to be found in native form, and pure praseodymium metal slowly develops a green oxide coating when exposed to air.

Praseodymium always occurs naturally together with the other rare-earth metals. It is the sixth-most abundant rare-earth element and fourth-most abundant lanthanide, making up 9.1 parts per million of the Earth's crust, an abundance similar to that of boron. In 1841, Swedish chemist Carl Gustav Mosander extracted a rare-earth oxide residue he called didymium from a residue he called "lanthana", in turn separated from cerium salts. In 1885, the Austrian chemist Carl Auer von Welsbach separated didymium into two elements that gave salts of different colours, which he named praseodymium and neodymium. The name praseodymium comes from the Ancient Greek πράσινος (prasinos), meaning 'leek-green', and δίδυμος (didymos) 'twin'.

Like most rare-earth elements, praseodymium most readily forms the +3 oxidation state, which is the only stable state in aqueous solution, although the +4 oxidation state is known in some solid compounds and, uniquely among the lanthanides, the +5 oxidation state is attainable in matrix-isolation conditions. The 0, +1, and +2 oxidation states are rarely found. Aqueous praseodymium ions are yellowish-green, and similarly, praseodymium results in various shades of yellow-green when incorporated into glasses. Many of praseodymium's industrial uses involve its ability to filter yellow light from light sources.

Physical properties

Praseodymium is the third member of the lanthanide series, and a member of the rare-earth metals. In the periodic table, it appears between the lanthanides cerium to its left and neodymium to its right, and above the actinide protactinium. It is a ductile metal with a hardness comparable to that of silver.[8] Praseodymium is calculated to have a very large atomic radius; with a radius of 247 pm, barium, rubidium and caesium are larger.[9] However, observationally, it is usually 185 pm.[10] Praseodymium's 59 electrons are arranged in the configuration [Xe]4f36s2; theoretically, all five outer electrons can act as valence electrons, but the use of all five requires extreme conditions and normally, praseodymium only gives up three or sometimes four electrons in its compounds.[11]

Like most other metals in the lanthanide series, praseodymium usually only uses three electrons as valence electrons, as afterward the remaining 4f electrons are too strongly bound: this is because the 4f orbitals penetrate the most through the inert xenon core of electrons to the nucleus, followed by 5d and 6s, and this increases with higher ionic charge. Praseodymium nevertheless can continue losing a fourth and even occasionally a fifth valence electron because it comes very early in the lanthanide series, where the nuclear charge is still low enough and the 4f subshell energy high enough to allow the removal of further valence electrons.[12] Thus, similarly to the other early trivalent lanthanides, praseodymium has a double hexagonal close-packed crystal structure at room temperature. At about 560 °C, it transitions to a face-centered cubic structure, and a body-centered cubic structure appears shortly before the melting point of 935 °C.[13]

Praseodymium, like all of the lanthanides, is paramagnetic at room temperature.[14] Unlike some other rare-earth metals, which show antiferromagnetic or ferromagnetic ordering at low temperatures, praseodymium is paramagnetic at all temperatures above 1 K.[5]

Chemical properties

Praseodymium(III) hydroxide

Praseodymium metal tarnishes slowly in air, forming a spalling green oxide layer like iron rust; a centimetre-sized sample of praseodymium metal corrodes completely in about a year.[15] It burns readily at 150 °C to form praseodymium(III,IV) oxide, a nonstoichiometric compound approximating to Pr6O11:[16]

12 Pr + 11 O2 → 2 Pr6O11

This may be reduced to praseodymium(III) oxide (Pr2O3) with hydrogen gas.[17] Praseodymium(IV) oxide, PrO2, is the most oxidised product of the combustion of praseodymium and can be obtained by either reaction of praseodymium metal with pure oxygen at 400 °C and 282 bar[17] or by disproportionation of Pr6O11 in boiling acetic acid.[18][19] The reactivity of praseodymium conforms to periodic trends, as it is one of the first and thus one of the largest lanthanides.[12] At 1000 °C, many praseodymium oxides with composition PrO2−x exist as disordered, nonstoichiometric phases with 0 < x < 0.25, but at 400–700 °C the oxide defects are instead ordered, creating phases of the general formula PrnO2n−2 with n = 4, 7, 9, 10, 11, 12, and ∞. These phases PrOy are sometimes labelled α and β′ (nonstoichiometric), β (y = 1.833), δ (1.818), ε (1.8), ζ (1.778), ι (1.714), θ, and σ.[20]

Praseodymium is an electropositive element and reacts slowly with cold water and quite quickly with hot water to form praseodymium(III) hydroxide:[16]

2 Pr (s) + 6 H2O (l) → 2 Pr(OH)3 (aq) + 3 H2 (g)

Praseodymium metal reacts with all the stable halogens to form trihalides:[16]

2 Pr (s) + 3 F2 (g) → 2 PrF3 (s) [green]
2 Pr (s) + 3 Cl2 (g) → 2 PrCl3 (s) [green]
2 Pr (s) + 3 Br2 (g) → 2 PrBr3 (s) [green]
2 Pr (s) + 3 I2 (g) → 2 PrI3 (s)

The tetrafluoride, PrF4, is also known, and is produced by reacting a mixture of sodium fluoride and praseodymium(III) fluoride with fluorine gas, producing Na2PrF6, following which sodium fluoride is removed from the reaction mixture with liquid hydrogen fluoride.[21] Additionally, praseodymium forms a bronze diiodide; like the diiodides of lanthanum, cerium, and gadolinium, it is a praseodymium(III) electride compound.[21]

Praseodymium dissolves readily in dilute sulfuric acid to form solutions containing the chartreuse Pr3+ ions, which exist as [Pr(H2O)9]3+ complexes:[16][22]

2 Pr (s) + 3 H2SO4 (aq) → 2 Pr3+ (aq) + 3 SO2−
4 (aq) + 3 H2 (g)

Dissolving praseodymium(IV) compounds in water does not result in solutions containing the yellow Pr4+ ions;[23] because of the high positive standard reduction potential of the Pr4+/Pr3+ couple at +3.2 V, these ions are unstable in aqueous solution, oxidising water and being reduced to Pr3+. The value for the Pr3+/Pr couple is −2.35 V.[11] However, in highly basic aqueous media, Pr4+ ions can be generated by oxidation with ozone.[24]

Although praseodymium(V) in the bulk state is unknown, the existence of praseodymium in its +5 oxidation state (with the stable electron configuration of the preceding noble gas xenon) under noble-gas matrix isolation conditions was reported in 2016. The species assigned to the +5 state were identified as [PrO2]+, its O2 and Ar adducts, and PrO2(η2-O2).[25]

Organopraseodymium compounds

Organopraseodymium compounds are very similar to those of the other lanthanides, as they all share an inability to undergo π backbonding. They are thus mostly restricted to the mostly ionic cyclopentadienides (isostructural with those of lanthanum) and the σ-bonded simple alkyls and aryls, some of which may be polymeric.[26] The coordination chemistry of praseodymium is largely that of the large, electropositive Pr3+ ion, and is thus largely similar to those of the other early lanthanides La3+, Ce3+, and Nd3+. For instance, like lanthanum, cerium, and neodymium, praseodymium nitrates form both 4:3 and 1:1 complexes with 18-crown-6, whereas the middle lanthanides from promethium to gadolinium can only form the 4:3 complex and the later lanthanides from terbium to lutetium cannot successfully coordinate to all the ligands. Such praseodymium complexes have high but uncertain coordination numbers and poorly defined stereochemistry, with exceptions resulting from exceptionally bulky ligands such as the tricoordinate [Pr{N(SiMe3)2}3]. There are also a few mixed oxides and fluorides involving praseodymium(IV), but it does not have an appreciable coordination chemistry in this oxidation state like its neighbour cerium.[27] However, the first example of a molecular complex of praseodymium(IV) has recently been reported.[28]

Isotopes

Praseodymium has only one stable and naturally occurring isotope, 141Pr. It is thus a mononuclidic and monoisotopic element, and its standard atomic weight can be determined with high precision as it is a constant of nature. This isotope has 82 neutrons, which is a magic number that confers additional stability.[29] This isotope is produced in stars through the s- and r-processes (slow and rapid neutron capture, respectively).[30] Thirty-eight other radioisotopes have been synthesized. All of these isotopes have half-lives under a day (and most under a minute), with the single exception of 143Pr with a half-life of 13.6 days. Both 143Pr and 141Pr occur as fission products of uranium. The primary decay mode of isotopes lighter than 141Pr is positron emission or electron capture to isotopes of cerium, while that of heavier isotopes is beta decay to isotopes of neodymium.[29]

History

Carl Auer von Welsbach (1858–1929), discoverer of praseodymium in 1885.

In 1751, the Swedish mineralogist Axel Fredrik Cronstedt discovered a heavy mineral from the mine at Bastnäs, later named cerite. Thirty years later, the fifteen-year-old Wilhelm Hisinger, from the family owning the mine, sent a sample of it to Carl Scheele, who did not find any new elements within. In 1803, after Hisinger had become an ironmaster, he returned to the mineral with Jöns Jacob Berzelius and isolated a new oxide, which they named ceria after the dwarf planet Ceres, which had been discovered two years earlier.[31] Ceria was simultaneously and independently isolated in Germany by Martin Heinrich Klaproth.[32] Between 1839 and 1843, ceria was shown to be a mixture of oxides by the Swedish surgeon and chemist Carl Gustaf Mosander, who lived in the same house as Berzelius; he separated out two other oxides, which he named lanthana and didymia.[33][34][35] He partially decomposed a sample of cerium nitrate by roasting it in air and then treating the resulting oxide with dilute nitric acid. The metals that formed these oxides were thus named lanthanum and didymium.[36][37]

While lanthanum turned out to be a pure element, didymium was not and turned out to be only a mixture of all the stable early lanthanides from praseodymium to europium, as had been suspected by Marc Delafontaine after spectroscopic analysis, though he lacked the time to pursue its separation into its constituents. The heavy pair of samarium and europium were only removed in 1879 by Paul-Émile Lecoq de Boisbaudran and it was not until 1885 that Carl Auer von Welsbach separated didymium into praseodymium and neodymium.[38] Von Welsbach confirmed the separation by spectroscopic analysis, but the products were of relatively low purity. Since neodymium was a larger constituent of didymium than praseodymium, it kept the old name with disambiguation, while praseodymium was distinguished by the leek-green colour of its salts (Greek πρασιος, "leek green").[39] The composite nature of didymium had previously been suggested in 1882 by Bohuslav Brauner, who did not experimentally pursue its separation.[40]

Occurrence and production

Praseodymium is not particularly rare, despite it being in the rare-earth metals, making up 9.2 mg/kg of the Earth's crust. This value is between those of thorium (9.6 mg/kg) and samarium (7.05 mg/kg), and makes praseodymium the fourth-most abundant of the lanthanides, behind cerium (66.5 mg/kg), neodymium (41.5 mg/kg), and lanthanum (39 mg/kg); it is less abundant than the rare-earth elements yttrium (33 mg/kg) and scandium (22 mg/kg).[39] Instead, praseodymium's classification as a rare-earth metal comes from its rarity relative to "common earths" such as lime and magnesia, the few known minerals containing it for which extraction is commercially viable, as well as the length and complexity of extraction.[41] Although not particularly rare, praseodymium is never found as a dominant rare earth in praseodymium-bearing minerals. It is always preceded by cerium and lanthanum and usually also by neodymium.[42]

The Pr3+ ion is similar in size to the early lanthanides of the cerium group (those from lanthanum up to samarium and europium) that immediately follow in the periodic table, and hence it tends to occur along with them in phosphate, silicate and carbonate minerals, such as monazite (MIIIPO4) and bastnäsite (MIIICO3F), where M refers to all the rare-earth metals except scandium and the radioactive promethium (mostly Ce, La, and Y, with somewhat less Nd and Pr).[39] Bastnäsite is usually lacking in thorium and the heavy lanthanides, and the purification of the light lanthanides from it is less involved. The ore, after being crushed and ground, is first treated with hot concentrated sulfuric acid, evolving carbon dioxide, hydrogen fluoride, and silicon tetrafluoride. The product is then dried and leached with water, leaving the early lanthanide ions, including lanthanum, in solution.[39]

The procedure for monazite, which usually contains all the rare earth, as well as thorium, is more involved. Monazite, because of its magnetic properties, can be separated by repeated electromagnetic separation. After separation, it is treated with hot concentrated sulfuric acid to produce water-soluble sulfates of rare earth. The acidic filtrates are partially neutralized with sodium hydroxide to pH 3–4, during which thorium precipitates as hydroxide and is removed. The solution is treated with ammonium oxalate to convert rare earth to their insoluble oxalates, the oxalates are converted to oxides by annealing, and the oxides are dissolved in nitric acid. This last step excludes one of the main components, cerium, whose oxide is insoluble in HNO3.[43] Care must be taken when handling some of the residues as they contain 228Ra, the daughter of 232Th, which is a strong gamma emitter.[39]

Praseodymium may then be separated from the other lanthanides via ion-exchange chromatography, or by using a solvent such as tributyl phosphate where the solubility of Ln3+ increases as the atomic number increases. If ion-exchange chromatography is used, the mixture of lanthanides is loaded into one column of cation-exchange resin and Cu2+ or Zn2+ or Fe3+ is loaded into the other. An aqueous solution of a complexing agent, known as the eluant (usually triammonium edtate), is passed through the columns, and Ln3+ is displaced from the first column and redeposited in a compact band at the top of the column before being re-displaced by NH+
4. The Gibbs free energy of formation for Ln(edta·H) complexes increases along with the lanthanides by about one quarter from Ce3+ to Lu3+, so that the Ln3+ cations descend the development column in a band and are fractionated repeatedly, eluting from heaviest to lightest. They are then precipitated as their insoluble oxalates, burned to form the oxides, and then reduced to metals.[39]

Applications

Leo Moser (not to be confused with the mathematician of the same name), son of Ludwig Moser, founder of the Moser Glassworks in what is now Karlovy Vary in the Czech Republic, investigated the use of praseodymium in glass coloration in the late 1920s, yielding a yellow-green glass given the name "Prasemit". However, at that time far cheaper colorants could give a similar color, so Prasemit was not popular, few pieces were made, and examples are now extremely rare. Moser also blended praseodymium with neodymium to produce "Heliolite" glass ("Heliolit" in German), which was more widely accepted. The first enduring commercial use of purified praseodymium, which continues today, is in the form of a yellow-orange "Praseodymium Yellow" stain for ceramics, which is a solid solution in the zircon lattice. This stain has no hint of green in it; by contrast, at sufficiently high loadings, praseodymium glass is distinctly green rather than pure yellow.[44]

Like many other lanthanides, praseodymium's shielded f-orbitals allow for long excited state lifetimes and high luminescence yields. Pr3+ as a dopant ion therefore sees many applications in optics and photonics. These include DPSS-lasers, single-mode fiber optical amplifiers,[45] fiber lasers,[46] upconverting nanoparticles[47][48] as well as activators in red, green, blue, and ultraviolet phosphors.[49] Silicate crystals doped with praseodymium ions have also been used to slow a light pulse down to a few hundred meters per second.[50]

As the lanthanides are so similar, praseodymium can substitute for most other lanthanides without significant loss of function, and indeed many applications such as mischmetal and ferrocerium alloys involve variable mixes of several lanthanides, including small quantities of praseodymium. The following more modern applications involve praseodymium specifically or at least praseodymium in a small subset of the lanthanides:[49]

Due to its role in permanent magnets used for wind turbines, it has been argued that praseodymium will be one of the main objects of geopolitical competition in a world running on renewable energy. However, this perspective has been criticized for failing to recognize that most wind turbines do not use permanent magnets and for underestimating the power of economic incentives for expanded production.[56][57]

Praseodymium
Hazards
GHS labelling:
GHS02: Flammable
Danger
H250
P222, P231, P422[58]
NFPA 704 (fire diamond)
NFPA 704 four-colored diamond
0
4
4

Biological role and precautions

The early lanthanides have been found to be essential to some methanotrophic bacteria living in volcanic mudpots, such as Methylacidiphilum fumariolicum: lanthanum, cerium, praseodymium, and neodymium are about equally effective.[59][60] Praseodymium is otherwise not known to have a biological role in any other organisms, but it is not very toxic either. Intravenous injection of rare earths into animals has been known to impair liver function, but the main side effects from inhalation of rare-earth oxides in humans come from radioactive thorium and uranium impurities.[49]

References

  1. ↑ "praseodymium". Oxford English Dictionary (Online ed.). Oxford University Press. (Subscription or participating institution membership required.)
  2. ↑ "Standard Atomic Weights: Praseodymium". CIAAW. 2017.
  3. ↑ Yttrium and all lanthanides except Ce and Pm have been observed in the oxidation state 0 in bis(1,3,5-tri-t-butylbenzene) complexes, see Cloke, F. Geoffrey N. (1993). "Zero Oxidation State Compounds of Scandium, Yttrium, and the Lanthanides". Chem. Soc. Rev. 22: 17–24. doi:10.1039/CS9932200017. and Arnold, Polly L.; Petrukhina, Marina A.; Bochenkov, Vladimir E.; Shabatina, Tatyana I.; Zagorskii, Vyacheslav V.; Cloke (15 December 2003). "Arene complexation of Sm, Eu, Tm and Yb atoms: a variable temperature spectroscopic investigation". Journal of Organometallic Chemistry. 688 (1–2): 49–55. doi:10.1016/j.jorganchem.2003.08.028.
  4. ↑ Chen, Xin; et al. (13 December 2019). "Lanthanides with Unusually Low Oxidation States in the PrB3– and PrB4– Boride Clusters". Inorganic Chemistry. 58 (1): 411–418. doi:10.1021/acs.inorgchem.8b02572. PMID 30543295. S2CID 56148031.
  5. 1 2 Jackson, M. (2000). "Magnetism of Rare Earth" (PDF). The IRM quarterly. 10 (3): 1.
  6. ↑ Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  7. ↑ Kondev, F. G.; Wang, M.; Huang, W. J.; Naimi, S.; Audi, G. (2021). "The NUBASE2020 evaluation of nuclear properties" (PDF). Chinese Physics C. 45 (3): 030001. doi:10.1088/1674-1137/abddae.
  8. 1 2 3 Lide, D. R., ed. (2005). CRC Handbook of Chemistry and Physics (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  9. ↑ Clementi, E.; Raimond, D. L.; Reinhardt, W. P. (1967). "Atomic Screening Constants from SCF Functions. II. Atoms with 37 to 86 Electrons". Journal of Chemical Physics. 47 (4): 1300–1307. Bibcode:1967JChPh..47.1300C. doi:10.1063/1.1712084.
  10. ↑ Slater, J. C. (1964). "Atomic Radii in Crystals". Journal of Chemical Physics. 41 (10): 3199–3205. Bibcode:1964JChPh..41.3199S. doi:10.1063/1.1725697.
  11. 1 2 Greenwood and Earnshaw, pp. 1232–5
  12. 1 2 Greenwood and Earnshaw, pp. 1235–8
  13. ↑ "Phase Diagrams of the Elements", David A. Young, UCRL-51902 "Prepared for the U.S. Energy Research & Development Administration under contract No. W-7405-Eng-48".
  14. ↑ Cullity, B. D.; Graham, C. D. (2011). Introduction to Magnetic Materials. John Wiley & Sons. ISBN 978-1-118-21149-6.
  15. ↑ "Rare-Earth Metal Long Term Air Exposure Test". Retrieved 8 August 2009.
  16. 1 2 3 4 "Chemical reactions of Praseodymium". Webelements. Retrieved 9 July 2016.
  17. 1 2 Greenwood and Earnshaw, pp. 1238–9
  18. ↑ Brauer, G.; Pfeiffer, B. (1963). "Hydrolytische spaltung von höheren oxiden des Praseodyms und des terbiums". Journal of the Less Common Metals. 5 (2): 171–176. doi:10.1016/0022-5088(63)90010-9.
  19. ↑ Minasian, S.G.; Batista, E.R.; Booth, C.H.; Clark, D.L.; Keith, J.M.; Kozimor, S.A.; Lukens, W.W.; Martin, R.L.; Shuh, D.K.; Stieber, C.E.; Tylisczcak, T.; Wen, Xiao-dong (2017). "Quantitative Evidence for Lanthanide-Oxygen Orbital Mixing in CeO2, PrO2, and TbO2" (PDF). Journal of the American Chemical Society. 139 (49): 18052–18064. doi:10.1021/jacs.7b10361. OSTI 1485070. PMID 29182343. S2CID 5382130.
  20. ↑ Greenwood and Earnshaw, pp. 643–4
  21. 1 2 Greenwood and Earnshaw, p. 1240–2
  22. ↑ Greenwood and Earnshaw, pp. 1242–4
  23. ↑ Sroor, Farid M.A.; Edelmann, Frank T. (2012). "Lanthanides: Tetravalent Inorganic". Encyclopedia of Inorganic and Bioinorganic Chemistry. doi:10.1002/9781119951438.eibc2033. ISBN 978-1-119-95143-8.
  24. ↑ Hobart, D.E.; Samhoun, K.; Young, J.P.; Norvell, V.E.; Mamantov, G.; Peterson, J. R. (1980). "Stabilization of Praseodymium(IV) and Terbium(IV) in Aqueous Carbonate Solution". Inorganic and Nuclear Chemistry Letters. 16 (5): 321–328. doi:10.1016/0020-1650(80)80069-9.
  25. ↑ Zhang, Qingnan; Hu, Shu-Xian; Qu, Hui; Su, Jing; Wang, Guanjun; Lu, Jun-Bo; Chen, Mohua; Zhou, Mingfei; Li, Jun (6 June 2016). "Pentavalent Lanthanide Compounds: Formation and Characterization of Praseodymium(V) Oxides". Angewandte Chemie International Edition. 55 (24): 6896–6900. doi:10.1002/anie.201602196. ISSN 1521-3773. PMID 27100273.
  26. ↑ Greenwood and Earnshaw, pp. 1248–9
  27. ↑ Greenwood and Earnshaw, pp. 1244–8
  28. ↑ Willauer, A.R.; Palumbo, C.T.; Fadaei-Tirani, F.; Zivkovic, I.; Douair, I.; Maron, L.; Mazzanti, M. (2020). "Accessing the +IV Oxidation State in Molecular Complexes of Praseodymium". Journal of the American Chemical Society. 142 (12): 489–493. doi:10.1021/jacs.0c01204. PMID 32134644. S2CID 212564931.
  29. 1 2 Audi, Georges; Bersillon, Olivier; Blachot, Jean; Wapstra, Aaldert Hendrik (2003), "The NUBASE evaluation of nuclear and decay properties", Nuclear Physics A, 729: 3–128, Bibcode:2003NuPhA.729....3A, doi:10.1016/j.nuclphysa.2003.11.001
  30. ↑ Cameron, A. G. W. (1973). "Abundance of the Elements in the Solar System" (PDF). Space Science Reviews. 15 (1): 121–146. Bibcode:1973SSRv...15..121C. doi:10.1007/BF00172440. S2CID 120201972. Archived from the original (PDF) on 21 October 2011.
  31. ↑ Emsley, pp. 120–5
  32. ↑ Greenwood and Earnshaw, p. 1424
  33. ↑ Weeks, Mary Elvira (1932). "The Discovery of the Elements: XI. Some Elements Isolated with the Aid of Potassium and Sodium:Zirconium, Titanium, Cerium and Thorium". The Journal of Chemical Education. 9 (7): 1231–1243. Bibcode:1932JChEd...9.1231W. doi:10.1021/ed009p1231.
  34. ↑ Weeks, Mary Elvira (1956). The discovery of the elements (6th ed.). Easton, PA: Journal of Chemical Education.
  35. ↑ Marshall, James L.; Marshall, Virginia R. (Winter 2015). "Rediscovery of the elements: The Rare Earths – The Confusing Years" (PDF). The Hexagon: 72–77.
  36. ↑ (Berzelius) (1839) "Nouveau métal" (New metal), Comptes rendus, 8 : 356–357. From p. 356: "L'oxide de cérium, extrait de la cérite par la procédé ordinaire, contient à peu près les deux cinquièmes de son poids de l'oxide du nouveau métal qui ne change que peu les propriétés du cérium, et qui s'y tient pour ainsi dire caché. Cette raison a engagé M. Mosander à donner au nouveau métal le nom de Lantane." (The oxide of cerium, extracted from cerite by the usual procedure, contains almost two fifths of its weight in the oxide of the new metal, which differs only slightly from the properties of cerium, and which is held in it so to speak "hidden". This reason motivated Mr. Mosander to give to the new metal the name Lantane.)
  37. ↑ (Berzelius) (1839) "Latanium — a new metal," Philosophical Magazine, new series, 14 : 390–391.
  38. ↑ Fontani, Marco; Costa, Mariagrazia; Orna, Virginia (2014). The Lost Elements: The Periodic Table's Shadow Side. Oxford University Press. pp. 122–123. ISBN 978-0-19-938334-4.
  39. 1 2 3 4 5 6 Greenwood and Earnshaw, p. 1229–32
  40. ↑ Fontani, Marco; Costa, Mariagrazia; Orna, Virginia (2014). The Lost Elements: The Periodic Table's Shadow Side. Oxford University Press. p. 40. ISBN 978-0-19-938334-4.
  41. ↑ Patnaik, Pradyot (2003). Handbook of Inorganic Chemical Compounds. McGraw-Hill. pp. 444–446. ISBN 978-0-07-049439-8. Retrieved 6 June 2009.
  42. ↑ Hudson Institute of Mineralogy (1993–2018). "Mindat.org". www.mindat.org. Retrieved 14 January 2018.
  43. ↑ Patnaik 2007, pp. 478–479.
  44. ↑ Kreidl, Norbert J. (1942). "RARE EARTHS*". Journal of the American Ceramic Society. 25 (5): 141–143. doi:10.1111/j.1151-2916.1942.tb14363.x.
  45. ↑ Jha, A.; Naftaly, M.; Jordery, S.; Samson, B. N.; et al. (1995). "Design and fabrication of Pr3+-doped fluoride glass optical fibres for efficient 1.3 mu m amplifiers" (PDF). Pure and Applied Optics: Journal of the European Optical Society Part A. 4 (4): 417. Bibcode:1995PApOp...4..417J. doi:10.1088/0963-9659/4/4/019.
  46. ↑ Smart, R.G.; Hanna, D.C.; Tropper, A.C.; Davey, S.T.; Carter, S.F.; Szebesta, D. (1991). "Cw room temperature upconversion lasing at blue, green and red wavelengths in infrared-pumped Pr3+-doped fluoride fibre". Electronics Letters. 27 (14): 1307. Bibcode:1991ElL....27.1307S. doi:10.1049/el:19910817.
  47. ↑ de Prinse, Thomas J.; Karami, Afshin; Moffatt, Jillian E.; Payten, Thomas B.; Tsiminis, Georgios; Teixeira, Lewis Da Silva; Bi, Jingxiu; Kee, Tak W.; Klantsataya, Elizaveta; Sumby, Christopher J.; Spooner, Nigel A. (2021). "Dual Laser Study of Non‐Degenerate Two Wavelength Upconversion Demonstrated in Sensitizer‐Free NaYF 4 :Pr Nanoparticles". Advanced Optical Materials. 9 (7): 2001903. doi:10.1002/adom.202001903. hdl:2440/139814. ISSN 2195-1071. S2CID 234059121.
  48. ↑ Kolesov, Roman; Reuter, Rolf; Xia, Kangwei; Stöhr, Rainer; Zappe, Andrea; Wrachtrup, Jörg (31 October 2011). "Super-resolution upconversion microscopy of praseodymium-doped yttrium aluminum garnet nanoparticles". Physical Review B. 84 (15): 153413. Bibcode:2011PhRvB..84o3413K. doi:10.1103/PhysRevB.84.153413. ISSN 1098-0121.
  49. 1 2 3 4 5 McGill, Ian. "Rare Earth Elements". Ullmann's Encyclopedia of Industrial Chemistry. Vol. 31. Weinheim: Wiley-VCH. p. 183–227. doi:10.1002/14356007.a22_607. ISBN 978-3527306732.
  50. ↑ "ANU team stops light in quantum leap". Retrieved 18 May 2009.
  51. ↑ Rare Earth Elements 101 Archived 2013-11-22 at the Wayback Machine, IAMGOLD Corporation, April 2012, pp. 5, 7.
  52. 1 2 Emsley, pp. 423–5
  53. ↑ Rokhlin, L. L. (2003). Magnesium alloys containing rare earth metals: structure and properties. CRC Press. ISBN 978-0-415-28414-1.
  54. ↑ Suseelan Nair, K.; Mittal, M. C. (1988). "Rare Earths in Magnesium Alloys". Materials Science Forum. 30: 89–104. doi:10.4028/www.scientific.net/MSF.30.89. S2CID 136992837.
  55. ↑ Borchert, Y.; Sonstrom, P.; Wilhelm, M.; Borchert, H.; et al. (2008). "Nanostructured Praseodymium Oxide: Preparation, Structure, and Catalytic Properties". Journal of Physical Chemistry C. 112 (8): 3054. doi:10.1021/jp0768524.
  56. ↑ Overland, Indra (1 March 2019). "The geopolitics of renewable energy: Debunking four emerging myths". Energy Research & Social Science. 49: 36–40. doi:10.1016/j.erss.2018.10.018. ISSN 2214-6296.
  57. ↑ Klinger, Julie Michelle (2017). Rare earth frontiers : from terrestrial subsoils to lunar landscapes. Ithaca, NY: Cornell University Press. ISBN 978-1501714603. JSTOR 10.7591/j.ctt1w0dd6d.
  58. ↑ "Praseodymium 261173".
  59. ↑ Pol, Arjan; Barends, Thomas R. M.; Dietl, Andreas; Khadem, Ahmad F.; Eygensteyn, Jelle; Jetten, Mike S. M.; Op Den Camp, Huub J. M. (2013). "Rare earth metals are essential for methanotrophic life in volcanic mudpots". Environmental Microbiology. 16 (1): 255–64. doi:10.1111/1462-2920.12249. PMID 24034209.
  60. ↑ Kang, L.; Shen, Z.; Jin, C. (2000). "Neodymium cations Nd3+ were transported to the interior of Euglena gracilis". Chin. Sci. Bull. 45 (277): 585–592. Bibcode:2000ChSBu..45..585K. doi:10.1007/BF02886032. S2CID 95983365.

Bibliography

Further reading

  • R. J. Callow, The Industrial Chemistry of the Lanthanons, Yttrium, Thorium, and Uranium, Pergamon Press, 1967.
  • Bouhani, H (2020). "Engineering the magnetocaloric properties of PrVO3 epitaxial oxide thin films by strain effects". Applied Physics Letters. 117 (7). arXiv:2008.09193. doi:10.1063/5.0021031.
Wikimedia Commons has media related to Praseodymium.
Look up praseodymium in Wiktionary, the free dictionary.
This article is issued from Wikipedia. The text is licensed under Creative Commons - Attribution - Sharealike. Additional terms may apply for the media files.